Study on the Effect of External Potential Field and Addition of Inorganic Particles on the Orientation and Crystallization of Polymer via Monte Carlo Simulation
The Monte Carlo simulation of a polymer system blended with inorganic particles was performed on a three dimension lattice to study the details of the ordered and disordered states of polymers under an external potential field. First, by assuming an external energy E<,p> and an intra-molecular energy E <,a> determined by the energy difference between the trans-conformation and cis-conformation, we simulated the three-dimensional distribution of the polymer system under different external potential fields and found the relationship between external field and the state of the ordered polymer system. Secondly, we generated a polymer system blended with inorganic particles and then simulated how these additional particles accelerate nucleation when polymer undergoes crystallization.
Monte Carlo simulation external potential field inorganic additional particle orientation crystallization polymer
HU Xilong WU Chengxun
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, P. R. China College of Material Science and Engineering, Donghua University, Shanghai 200051, P. R. China
国际会议
上海
英文
53-55
2007-10-15（万方平台首次上网日期，不代表论文的发表时间）