Kinetics Study on Remote Argon Plasma-Induced Graft Polymerization of Acrylic Acid onto PTFE Films
In this paper, we introduced carboxylic groups on the surface of poly (tetrafluoroethylene) (PTFE) with the aid of remote argon plasma treatment and the post- grafting of acrylic acid (AAc) in an aqueous solution. We chose different parameters of remote plasma treatment to get the optimum condition for grafting co-polymerization AAc on the PTFE surface. The influence of the grafting reaction conditions on the grafting degree was investigated. The apparent activation energy of the grafting obtained from an Arrhenius plot was 27.2kJ/mol. The surface hydrophilicity of the PTFE film was characterized with the water contact angle meter and the surface free energy. The hydrophilicity of the PTFE film surface was greatly enhanced. The time-dependent activity of the grafted surface was better than that of the plasma treated film.
poly (tetrafluoroethylene) remote argon plasma acrylic acid graft polymerization
WANG Chen CHEN Jierong
College of textile and materials, Xian Polytechnic University, Xian 710048, P. R. China School of School of life science and technology, Xian Jiaotong University, Xian 710049, P. R. China
国际会议
上海
英文
655-658
2007-10-15（万方平台首次上网日期，不代表论文的发表时间）