Preparation and Characterization of Biodegradable Block Tercopolymer of TMC, LLA and ε-CL

摘要：

Biodegradable ABA-type tercopolymers of trimethylene carbonate (TMC), L-lactide (LLA) and ε-caprolactone (ε- CL) with weight ratio of 30/30/40 and 40/20/40 (TMC/LLA/ε-CL) were synthesized via bulk ringopening copolymerization, using stannous octoate as catalyst. The molecular structure of the tercopolymer was characterized by <13>C nuclear magnetic resonance (NMR), gel permeation chromatography (GPC) and fourier transform infrared (FTIR). The results showed that the novel poly (TMC-co-LLA)/poly(ε-CL) ABA type block tercopolymers were successfully synthesized.

关键词： trimethylene carbonate L-lactide ε-caprolactone block tercopolymer

作者: JIA Yongtang JIN Kun DONG Fengchun HEN Xinyuan

作者单位: College of Material Science and Chemical Engineering, Liaodong University, Dandong 118003, P. R. Chi Dalian University of Technology, State key Laboratory of Fine Chemicals, Dalian 116012, P. R. China College of Material Science and Chemical Engineering, Liaodong University, Dandong 118003, P. R. Chi College of Material Science and Engineering, Donghua University, Shanghai 201620, P. R. China

会议类型: 国际会议

会议名称: 2007年先进纤维与聚合物国际会议

会议地点: 上海

会议语种:英文

页码: 743-745

在线出版日期: 2007-10-15（万方平台首次上网日期，不代表论文的发表时间）