Highly Luminescent Host-Guest Systems Based on Zeolite L and Lanthanide Complexes

摘要：

Supramolecular incorporation of lanthanide complex has been obtained by loading of organic ligand into Eu<3+>-exchanged zeolite L. This was achieved by a two-step procedure: (1) zeolite L was ion-exchanged with Eu(Ⅲ) ions;(2) organic ligand was then loaded into the channels of the Eu<3+>-exchanged zeolite by gas diffusion procedure. Loading of ligand into the channels of zeolite L was confirmed by element analysis. Luminescence spectroscopy has confirmed that lanthanide complex are formed in the nanochannels of zeolite L crystals. In addition to the sharp emissions of lanthanide ions, broad band ranged from 350~500nm can also be observed. This study provides alternative method for fabricating full-color display materials.

关键词： lanthanide complex zeolite L host-guest luminescence sensitization rare earths

作者: Wang Yige(王弋戈) Guo Zhi(郭枝) Li Huanrong(李焕荣)

作者单位: School of Chemical engineering, Hebei University of Technology, Tianjin 300130, China

会议类型: 国际会议

会议名称: 第五届国际稀土开发与应用研讨会(The Fifth International Conference on Rare Earth Decelopment and Applicatin)

会议地点: 包头

会议语种:英文

页码: 283-285

在线出版日期: 2007-08-07（万方平台首次上网日期，不代表论文的发表时间）