Preparation of TiC and cracking of deoiled asphalt realized simultaneously by high energy ball-milling
Deoiled asphalt and titanium were milled by a planet ball milling in order to prepare TiC and examine the cracking behaviors of deoiled alphalt. The milled powder samples were characterized by X-ray diffraction (XRD) measurement and scanning electron microscope (SEM). The produced gases were analyzed by gas phase chromatography. The results indicated that the C-C bonds of the aromatic rings were broken into actived carbon atoms during milling process because of the inductive effect of Ti atoms. The carbon atoms provided element C for the fabrication of TiC by mechanical alloying. The H atoms of aromatic rings were released to form H<,2> The side chains are cracked into CH<,4> and C<,2>H<,6>. The effects of C/Ti ratio and the milling time on mechanical cracking and alloying were discussed in detail.
B. LI L. S. CUI Y. J. ZHENG C. M. XU
China University of Petroleum, Beijing
国际会议
首届世界重油大会(The Technical Sessions of the First World Heavy Oil Conference)
北京
英文
894-899
2006-11-12（万方平台首次上网日期，不代表论文的发表时间）