Gas-phase Cα=Cβ Double Bond Cleavage in the Dissociation of Protonated 2-benzylidene-cyclopentanones:Dissociative Proton Transfer and Intramolecular Pronton-transport Catalysis

摘要：

　　Among gas-phase dissociation reactions,double bond cleavage reaction appears to happen extremely rare,especially in the case of C=C double bond.In the dissociation reaction of protonated 2-benzylidenecyclopentanones in tandem mass spectrometry,the formation of benzyl cations was observed,resulting from the cleavage of C double bonds.A combined experimental and theoretical investigation on intramolecular hydrogen transfers was carried out to illustrate the mechanisms,which indicated that intramolecular proton-transport catalysis played a vital role in the reaction.

作者: Shanshan Shen Yunfeng Chai Lingzi Dai Chang Li Yuanjiang Pan

作者单位: Department of Chemistry,Zhejiang University,Hangzhou 310027 College of Pharmaceutical Sciences,Zhejiang University,Hangzhou 310058

会议类型: 国内会议

会议名称: 中国化学会第十九届全国有机分析及生物分析学术研讨会

会议地点: 成都

会议语种:英文

页码: 94-94

在线出版日期: 2017-03-30（万方平台首次上网日期，不代表论文的发表时间）