Synthesis of Chrysenopyrazoles and Fluorescence Properties

摘要：

　　Chrysenopyrazoles were synthesized from o-hydroxyacetophenones and aryl halides via four steps.Intermediate 3-phenyl-4-arylpyrazoles were obtained in good yields.Irradiating 3-phenyl-4-arylpyrazoles, dehydration product chrysenopyrazoles and dehydrogenation product hydroxy-chrysenopyrazoles were obtained in the meantime.The fluorescence properties of chrysenopyrazoles were determined, and hydroxy-chrysenopyrazolesemit yellowish-green light in alkalinity due to excited-state intramolecular proton transfer (ESIPT).

关键词： Chrysenopyrazoles ESIPT dehydration dehydrogenation fluorescence properties

作者: Chenchen Li Zunting Zhang Zhang Jin Longzhu Liu Tuo Ma

作者单位: Key Laboratory of the Ministry of Education for Medicinal Resources and Natural Pharmaceutical Chemistry, National Engineering Laboratory for Resource Development of Endangered Crude Drugs in Northwest of China, and School of Chemistry and School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi”an 710062, P.R.China

会议类型: 国内会议

会议名称: 中国化学会第十八届全国有机分析及生物分析学术研讨会

会议地点: 上海

会议语种:英文

页码: 44-46

在线出版日期: 2015-04-17（万方平台首次上网日期，不代表论文的发表时间）