From Thorium to Curium: Unprecedented Structures and Properties in Actinide Borates

摘要：

The use of molten boric acid as a reactive flux for synthesizing actinide borates has beendeveloped in the past two years providing access to a remarkable array of exotic materials withboth unusual structures and unprecedented properties.”ThB5O6(OH)6””BO(OH)2”·2.5H2Opossesses a cationic supertetrahedral structure and displays remarkable anion exchangeproperties with high selectivity for TcO4?.”1-3” Uranyl borates form noncentrosymmetricstructures with extraordinarily rich topological relationships.

作者: Shuao Wang Evgeny V. Alekseev Thomas E. Albrecht-Schmitt

作者单位: School of Radiation Medicine and Protection(SRMP)and School of Radiological and Interdisciplinary Sc Institute for Energy and Climate Research(IEK-6),Forschungszentrum Jülich GmbH,52428 Jülich,Germany Department of Chemistry and Biochemistry,Florida State University,102 Varsity Way,Tallahassee,Florid

会议类型: 国内会议

会议名称: 第二届全球华人辐射研究大会

会议地点: 苏州

会议语种:英文

页码: 219-221

在线出版日期: 2014-05-11（万方平台首次上网日期，不代表论文的发表时间）