Surprising Coordination for Thorium(Ⅳ) Organic Framework Structures based on a Graphene-Like (6,3) Sheet Topology
Over the past two decades, significant effort has been focused on the crystal chemistry of actinide elements which is heavily dominated by the linear (UO2)2+uranyl ion with an emphasis on its critical role in the traditional nuclear fuel cycle.In comparison, thorium is relatively less explored, mostly probably due to two reasons:first, thorium is not relevant to uranium based nuclear fuel cycle; second, the chemistry of thorium is not as rich as uranium since only tetravalent state of thorium dominates under normal conditions, despite that there is renewed interest on Th-232as nuclear fuel in the molten salt reactor in several countries, which may push further understanding on the solid state chemistry of thorium.
Yuxiang Li Zhehui Weng Yanlong Wang Shuao Wang
School for Radiological and Interdisciplinary Sciences (RAD-X), Soochow University;State Key Laborat Department of Chemical Science & Technology, Kunming University School for Radiological and Interdisciplinary Sciences (RAD-X), Soochow University
国内会议
南宁
英文
9-10
2015-11-27（万方平台首次上网日期，不代表论文的发表时间）