Adsorption of 2,3,7,8-tetrochlorodibenzo-p-dioxins on intrinsic,defected, and Ti (N, Ag) doped graphene: a DFT study
As one of the most hazardous substances in the world, dioxins have received continuous interest in chemistry.materials, and environmental sciences The rapid detection and capture of carcinogenic 2,3,7,8-tetrochlorodibenzo-pdiosin (TCDD) are particularly challenging in the fields of materils and environmental sciences.In this study, density functional theory (DFT) method was applied to systematically investigate the interactions between TCDD and different types of graphene samples.The results reveal that the initial configuration of TCDD affects the interactions to a certain extent.As TCDD molecule is parallel to the graphene sheets, the interactions are the largest for all three types of graphene samples (intrinsic, defected and doped).In addition, the ”TCDD” capture ability of graphene can be greatly improved by Ti doping.Our study facilitates the rational design of efficient sensors for a variety of applications in environmental science and engineering.
Density functional theory Doped Graphene 2,3,7,8-Tetrochlorodibenzo-p-dioxin(TCDD)
Hongping Zhang Weidong He Xuegang Luo Xiaoyan Lin Xiong Lu
Engineering Research Center of Biomass Materials,Ministry of Education,School of Ma(t)crials Science School of Energy Science and Engineering,University of Electronic Science and Technology of China (U Key Laboratory of Advanced Technologies of Materials,Ministry of Education,School of Materials Scien
国内会议
苏州
英文
719-719
2014-10-26（万方平台首次上网日期，不代表论文的发表时间）