Extinguishing Efficiency of Liquid Nitrogen against Trichlorosilane Fires
TCS (Trichlorosilane,SiHCl3 ) and other Chlorosilane were used abundantly in semiconductor and solar energy industries as the principal resource to generate ultrapure silicon in production.They are mostly acutely toxic,water-reactive and corrosive substances.While in the fires,TCS might form Silicon dioxide,Chlorine and Hydrogen gases and were difficult to extinguish.There were numerous fires due to TCS’s flammability,such as overturned truck in Michigan,US,1989 and leaking in solar manufacturer in Pingtung,Taiwan,2011.Many concerns aroused among the relevant agencies on how to put out fires and how to reduce hazards.Our study showed liquid nitrogen could yield extinguishing ability with its cooling and suffocation effects.Vaporizing liquid nitrogen drew the heat from combustion reaction and reduced the flammable vapor to quench flames.The key parameter was liquid nitrogen application in large amount could effectively extinguish TCS fires.Cooled TCS showed unchanged properties and still had potential to flame.
trichlorosilane (TCS) extinguishing liquid nitrogen
Liao Kuangyu Horng Jaojia Liou Kehun Liao Yuanchun Shen JyunHong
No.123,Sec. 3,Daxue Rd.,Douliu City,Yunlin County 640,Taiwan
国内会议
青岛
英文
135-147
2014-08-28（万方平台首次上网日期，不代表论文的发表时间）