One Zn(Ⅱ) Metal-Organic Polymer Based on 4-(1-H-imidazol-2-yl)Benzoic Acid ligand: Synthesis, Crystal Structure,Photoluminescent Property
One d10 polymer based on imidazole derivative, namely, ”Zn(Hiba)2”n (1)(H2iba =4-(1-H-imidazol-2-y1) benzoic acid) was synthesized under hydrothermal condition and was characterized by elemental analysis, IR spectroscopy, and single X-ray diffractions.Polymer 1 features 2D (4, 4) layer, which contains single left-handed and right-handed 1D chain.The Hiba ligands further link these 1D chains to form an overall 3D framework.The title polymer exhibited exceptional high thermal stability.The enhanced luminescence of the title polymer is attributed to the coordination of the d10 metal ion to amine acid like ligand, then followed by the formation of ligand to metal charge transfer (LMCT).
Lang Liu Xun Feng Li Ya Wang
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001, P.R.China College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, P.R.China College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, P.R.China;
国内会议
江西吉安
英文
116-116
2013-04-21（万方平台首次上网日期，不代表论文的发表时间）