Standard Enthalpies of Formation of Rare Earth L-Proline Chloride Complexes ”RE(L-Pro)2(H2O)5”Cl3 (RE=Ho, Er)

摘要：

　　Two crystalline compounds of rare-earth chlorides coordinated with L-proline,”RE(L-Pro)2(H2O)5”Cl3 (RE =Ho, Er), were synthesized.Their were characterized: ”RE(LPro)2(H2O)5”Cl3 (RE =Ho, Er) to be 98.85 % and 98.62 %, respectively.After the measurement of the dissolving heat of the two systems, at 298.15 K, △fHmθ””Ho(LPro)2(H2O)5”Cl3, s, 298.15 K” =-3675.0 ± 1.3 kJ·mol-1, AfHmθ””Er(L-Pro)2(H2O)5”Cl3, s,298.15 K” =-3655.9 ± 1.6 kJ·mol-1, respectively.

关键词： Microcalorimetric method rare-earth chloride with L-proline ”RE(LPro)2(H2O)5”Cl3 (RE =Ho, Er) standard enthalpy of formation

作者: Huang Jinxiu Li Haiyan

作者单位: College of Chemical Engineering, Beijing Institute of Petro-chemical Technology

会议类型: 国内会议

会议名称: 第二届北京市大学生科学研究与创业行动计划成果展示与经验交流会

会议地点: 北京

会议语种:英文

页码: 112-114

在线出版日期: 2013-04-01（万方平台首次上网日期，不代表论文的发表时间）