pH Responsivity, Thermal Properties and Surface Properties of Brush Copolymers with Different Backbone Structures:Random, Block,Gradient
pH-responsive brush copolymers based on block,random and gradient copolymers of methyl methacrylate (MMA) and 2-hydroxyethyl methacrylate (HEMA) as the backbone component and hydrophilic poly(acrylic acid) (PAA) as the side chain were synthesized by ATRP.The intermediates and final products were characterized by NMR,FTIR spectroscopy and GPC.The self-assembly behavior and pH responsivity of the copolymers were also investigated by TEM and DLS.Thermal behavior and surface properties were systematically investigated using DSC and static water contact angles (SWCA) respectively.Experimental results indicate that thermal properties,pH responsivity and surface properties of the brush copolymers are different due to the different backbone composition.
pH responsivity Thermal properties Surface properties Different backbone structure Brush copolymers
Jin-jin Li Zheng-Hong Luo
Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P R China
国内会议
武汉
英文
26-28
2012-10-16（万方平台首次上网日期，不代表论文的发表时间）