Synthesis and fluorescent properties of 3HNA-doped PMMA composites

摘要：

　　The composites of poly(methyl methacrylate) (PMMA) and 2-hydroxy-3-naphthoic acid (3HNA) were prepared by in situ polymerization.The effect of polar solvent N,N-dimethylacetamide (DMAc) on the fluorescent properties ofthe composites was investigated by fluorescence emission spectrum.The results indicate that the 3HNA-doped PMMA exhibits dual emissions,which are corresponding to the normal or large Stokes-shifted fluorescence of 3HNA and the excited state intramolecular proton transfer (ESIPT),respectively.The intensity of Stokes-shifted emission changes regularly with the concentration of 3HNA-doped PMMA in DMAe.

关键词： 2-hydroxy-3-naphthoic acid poly(methyl methacrylate) excited state intramolecular proton transfer fluorescence

作者: TANG Qiang LIN Meijuan WANG Xiaoping LING Qidan

作者单位: Fujian Key Laboratory of Polymer Materials, College of Materials Science and Engineering, Fujian Normal University, Fuzhou 350007

会议类型: 国内会议

会议名称: 2012年全国高分子材料科学与工程研讨会

会议地点: 武汉

会议语种:英文

页码: 63-67

在线出版日期: 2012-10-16（万方平台首次上网日期，不代表论文的发表时间）