Dissolution Properties of Ammonium Di(2,4,6,-rinitrophenyl)amide in N-methl-2-pyrrolidone
Ammonium Di(2,4,6,-trinitrophenyl)amide is a new high-nitrogen energetic compound which consists of anion of Di(2,4,6,-trinitrophenyl)amide and cation of Ammonium. The dissolution process was studied for the first, and the enthalpies of dissolution for ammonium Di(2,4,6,-trinitrophenyl)amide(ADTA) in N-methl-2-pyrrolidone (NMP) were measured using a RD496-2000 Calvet microcalorimeter(MianYang CP Thermal Analysis Instrument CO., LTD) at 298.15 K under atmospheric pressure. Empirical formulae for the calculation of the enthalpies of dissolution (△disaH), the linear relationships between the rate (k) and the molality of ADTA(b), and the corresponding kinetic equation describing this dissolution processe for ADTA in NMP were obtained from the experimental data of the dissolution processes of ADTA in NMP. We get
ammonium di(2 4 6 -trinitrophenyl)amide dissolution kinetics N-methl-2-pyrrolidone
Xiao Libai Zhao Fengqi Xing Xiaoling Zhou Zhiming Huang Haifeng An Ting Gao Hongxu TanYI
National Key Lab of Science and Technology on Combustion and Explosion, Xi”an Modem Chemistry Resear School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing, 100081
国内会议
中国化学会第三届全国热分析动力学与热动力学学术会议暨江苏省第三届热分析技术研讨会
南京
英文
133-134
2011-10-01（万方平台首次上网日期，不代表论文的发表时间）