Mercapto Thiadiazole-Based Sensor with Colorimetric Specific Selectivity for AcO- in Aqueous Solution

摘要：

A novel acetate selective anion sensor 3 based on azophenol and mercapto thiadiazole had been designed and synthesized. Sensor 3 behaves a single selectivity and sensitivity in the recognition for AcO* anion over other anions such as F‐, C1‐ Br‐, I‐, H2PO4‐, HSO4‐ and CIO4‐ by naked-eyes and UV-vis spectra changes in aqueous solution (H2O/DMSO, 5:5, v/v). 1H NMR titration results revealed that the binding process includes two steps: (I) hydrogen bonding interactions (for small quantities of acetate) and (ii) proton transfer between the sensor 3 and the coordinated anion (for high quantities of acetate).

关键词： acetate anion sensor aqueous solution single recognition naked-eyes

作者: Jun-Qiang Li Tai-Bao Wei Qi Lin Ping Li You-Ming Zhang

作者单位: Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China Key Labo Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China KeyLabor Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China Key Labo

会议类型: 国内会议

会议名称: 2011年中西部地区无机化学化工学术研讨会

会议地点: 兰州

会议语种:英文

页码: 41-43

在线出版日期: 2011-08-01（万方平台首次上网日期，不代表论文的发表时间）