A Novel Complez of Na(Ⅰ)-Nitronyl Nitrozide”Na(NIT-1”-MeBzIm)3”ClO4: Synthesis and Crystal Structure

摘要：

A novel complex ”Na(NIT-1”-MeBzIm)3”ClO4 (NIT-1”-MeBzIm=2-”2”-”(1”-methyl)benzimidazolyl””-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) has been prepared and structurally characterized by elemental analysis, IR spectra and X-ray diffraction methods. The title complex crystallizes in Trigonal,space group P-3, Z= 2. Crystal data: C45H57ClN12NaO10, Mr=984.47, a=13.9411(8), b=13.9411(8), c=14.8622(16) (A), γ= 120°,V= 2501.5(3) (A)3, Dc =1.307g/cm3, μ(MoKα) =0.152 mm-1, F(000) =1038, R=0.0637, wR =0.1813, for 1957 observed reflections with Ⅰ＞2σ(Ⅰ). X-ray analysis reveals that Na(I) ion is six-coordinated with three NIT-1”-MeBzIm radicals. As we known, the coordinated way of three radicals coordinating to Na(I) ion by chelated way in main group is the first example.

关键词： nitronyl nitrozide radical crystal structure Na complezes

作者: WANG Li-Ya(王利亚) YANG Rui-Hua(杨瑞华) JIANG Kai(蒋凯)

作者单位: Department of Chemistry,Luoyang Normal University,Luoyang 471022;College of Chemistry and Environmental Science,Henan Normal University,Xinxiang 453002

会议类型: 国内会议

会议名称: 2008年中西部地区无机化学、化工学术交流会

会议地点: 乌鲁木齐

会议语种:英文

页码: 118-119

在线出版日期: 2008-08-01（万方平台首次上网日期，不代表论文的发表时间）