KUMADA CHAIN-GROWTH POLYCONDENSATION FOR CONJUGATED AND UNCONJUGATED POLYMERS
To date most of the conjugated polymers are synthesized by transition metal complex (typically Ni and Pd-complexes) catalyzed cross-coupling reactions, and the polymerizations usually follow step-growth mechanism. Accordingly, molecular weight and polydispersity (PDI) of the resulting polymers are in general poorly controlled. In comparison, chaingrowth polymerizations are better controlled in term of these parameters. Particularly, block copolymers can be prepared via chain-growth polymerizations with living feature.
Yanhou Gene Shupeng Wu Li Huang Fosong Wang
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P.R.China
国际会议
PP’2010,Jinan International Symposium on Polymer Physics(2010济南国际高分子物理学术研讨会)
济南
英文
10-11
2010-06-06(万方平台首次上网日期,不代表论文的发表时间)