Synthesis of vegetable oil based polyether polyol via epoxidation followed by ring-opening reaction
Because petroleum is a nonrenewable resource, the preparation of polyols from relatively cheap and renewable natural oil is highly desired. In this study, the epoxidized cottonseed oil with epoxy oxygen content from 5.25 wt％ to 6.15 wt％ was first produced by peroxyformic acid generated in situ from hydrogen peroxide and formic acid, which means there were 2.8 to 3.3 epoxy groups exist in each epoxidized cottonseed oil molecule. Then the preparation of polyether polyols by the ring opening of the epoxidized cottonseed oil with sorbitol in the presence of a tetra-fluoroboric acid was explored.
vegetable oil epoxidation polyether polyols ring opening reaction
Jia Liankun Gong Lixiang Kan Chengyou
Department of Chemical Engineering and Laboratory of Advanced Materials of Education Ministry,Tsinghua University, Beijing 100084, China
国际会议
2010 Beijing International Bonding Technology Symposium(2010北京国际粘接技术研讨会)
北京
英文
251-254
2010-10-31（万方平台首次上网日期，不代表论文的发表时间）