Novel Synthetic Approaches of 1, 4, 5, 8-Tetranitro-1, 4, 5, 8-Tetraazadecalin(TNAD)

摘要：

Taking hydration glyoxal, ethylenediamine as primary material, Tetraazadecalin (TAD) was synthesized by aldehyde amine Cyclization, and Tetraazadecalin hydrochloride was obtained by acidification of TAD. Nitration of Tetraazadecalin Hydrochloride (CTAD) with a nitrating mixture of nitric acid and acetic anhydride gave 1, 4, 5, 8-Tetranitro-1, 4, 5, 8-tetraazadecalin (TNAD). The overall yield of TNAD is more than 43%. The purity of TNAD is no less than 98%. The structure of TNAD was characterized by IR, NMR and elemental analysis. Also, the basic properties were tested in this work.

关键词： piperazine nitrition synthesis characterization

作者: JI Yueping WANG Wei DING Feng XU Ruoqian YANG Wei

作者单位: Xian Modern Chemistry Research Institute, Xian 710065, Shaanxi, China

会议类型: 国际会议

会议名称: 2009 International Autumn Seminar on Propellants,Ezplosives and Pyrotechnics(2009国际推进剂、炸药、烟火技术秋季研讨会)

会议地点: 昆明

会议语种:英文

页码: 1-3

在线出版日期: 2009-09-22（万方平台首次上网日期，不代表论文的发表时间）