Structural study of molten MgCh and MgCU-LiCl system by X-ray diffraction
The structure of pure MgCl2 melt and MgCl2-LiCl molten system was investigated by X-ray diffraction technique. The estimation of structural parameter based on Debye equation was carried out by random optimization method. The structural parameters were calculated by assuming the MgCl42- units in the melts, and both ionic distance and coordination number were estimated for pairwise Mg-Cl, Cl-Cl, LiCl and Mg-Mg. An interesting result was obtained that the structure of Mg-Mg pair corresponding to second coordination sphere were changed to be of lower coordination number by addition of LiCl.
X-ray diffraction molten salt MgCl2 LiCl
T. Ohkubo Y. Iwadate
Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho Inage-ku, Chiba 263-8522, Japan
国际会议
The 3rd Asian Conference on Molten Salts and Ions Liquids 2011(第三届亚洲熔盐与离子液体会议)
哈尔滨
英文
55-58
2011-01-06（万方平台首次上网日期，不代表论文的发表时间）